Synthesis and characterization of aliphatic-aromatic polyesters using interfacial polycondensation technique
Thirteen linear aliphatic-aromatic polyesters were synthesized by interfacial polycondensation of various diacid chlorides such as adipoyl chloride (ADCL) and sebacoyl chloride (SECL) with various diols such as bisphenol-A (BPA), resorcinol (RES), 1,5-dihydroxy naphthalene(15DHN), 4,4’-bis(hydroxyl)benzilidine aniline (BHBA), 4,4’-bis(hydroxybenzilidine)benzidine(BHBB), 4,4’-bis(hydroxybenzilidine)-p- phenylenediamine (BHBP), 4,4’-bishydroxy biphenyl thioether (BHBPT) using chloroform-water interphase system, alkali as an acid acceptor and citramide as phase transfer catalyst at ambient tem